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Zinc-Nanoparticles Synthesis Mediated by Hexalobus Crispiflorus Bark Extract for Corrosion Inhibition on Mild Steel in Seawater

William-Porbeni, D., ., Ogbereyo, S, Osaribie, N.A., Mairo, J

Abstract

Corrosion control has seen a shift from the traditional corrosion control methods to a more plant mediated green approach. The application of plant mediated nanoparticle for corrosion inhibition has received much research interest in recent times. The aim of this study was the green synthesis of zinc nanoparticles mediated by Hexalobus Crispiflorus bark extracts and zinc nitrate hexahydrate as the precursor for corrosion inhibition on mild steel in seawater. Plant-based phytochemicals were used as natural reducing and stabilizing agents for nanoparticle synthesis. Phytochemicals analysis of extract bark showed the presence of flavonoids and terpenoids. A color change from dark brown to light brown was the first indicator of nanoparticle synthesis. The biosynthesized nanoparticles were characterized by UV-Vis, FTIR, SEM, XRD, and EDX analysis. XRD images showed several well-defined peaks at 2θ position corresponding to its crystallinity. Crystalline size of the nanoparticles was calculated using the scherrers equation to be 10.3nm. SEM micrographs showed aggregated particles with a rough texture. EDX confirmed the presence of zinc and oxygen in its elemental composition. Weight loss method was used to determine the corrosion inhibition on mild steel in sea water. Inhibition efficiency of 59.37% was obtained at the highest concentration of nanoparticles studied.

Keywords

; BiosynthesisCorrosionExtractsHexalobus crispiflorusInhibitionNanoparticlesZnNPs

References

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