Tailored Polyoxometalates (POMs) For Next-Generation Energy, Catalysis, and Environmental Remediation: Structural Design, Mechanistic Insight, and Application Frontiers

Abbas, H., Streb, C., Pickering, A. L., Neil, A. R., Long, D.L., & Cronin, L. (2008). Molecular growth of polyoxometalate architectures based on [Ag(Mo8)Ag] synthons: Toward designed cluster assemblies. Crystal Growth & Design, 8(2), 635–642. Al-Yasari, A., Van Steerteghem, N., Kearns, H., El Moll, H., Faulds, K., Wright, J. A., Brunschwig, B. S., Clays, K., & Fielden, J. (2017). Organoimido-polyoxometalate nonlinear optical chromophores: A structural, spectroscopic, and computational study. Inorganic Chemistry, 56(17), 10181–10194. Alves, L. S., Chen, L., Lemmon, C. E., Gembicky, M., Xu, M., & Schimpf, A. M. (2022). PEG- infiltrated polyoxometalate frameworks with flexible form-factors. ACS Materials Letters, 4(10), 1937–1943. Anyushin, A. V., Kondinski, A., & Parac Vogt, T. N. (2019). Hybrid polyoxometalates as post functionalization platforms: From fundamentals to emerging applications. Chemical Society Reviews, 49, 382–432. Aramesh, N., Bagheri, A. R., Zhang, Z., Yadollahi, B., & Lee, H. K. (2024). Polyoxometalate- based materials against environmental pollutants: A review. Coordination Chemistry Reviews, 507, Article 215767. Aureliano, M. (2022). The future is bright for polyoxometalates. BioChem, 2(1), 8–26. Bijelic, A., Aureliano, M., & Rompel, A. (2018). The antibacterial activity of polyoxometalates: Structures, mechanisms and potential applications. Chemical Communications, 54, 1153– 1169. Carino, C., Proust, A., Guillemot, G., K/Bidi, L., Blanchard, S., Gibson, E. A., & Izzet, G. (2025). Unveiling photoinduced electron transfers in photosensitized polyoxometalates for solar energy conversion. Chemical Science, 16(42), 19493–19518. Carraro, M., & Gross, S. (2014). Hybrid materials based on the embedding of organically modified transition metal oxoclusters or polyoxometalates into polymers for functional applications: A review. Materials, 7(5), 3956–3989. Chen, W., Zhou, Y., & Li, J. (2021). Polyoxometalates for heavy metal adsorption and reduction: Mechanistic insights and applications. Journal of Hazardous Materials, 416, 125854. Clegg, W., Elsegood, M. R., Errington, R. J., & Havelock, J. (1996). Alkoxide hydrolysis as a route to early transition-metal polyoxometalates: Synthesis and crystal structures of heteronuclear hexametalate derivatives. Journal of the Chemical Society, Dalton Transactions, (5), 681–690. Cronin, L., & Muller, A. (2012). Polyoxometalate chemistry: From topology via self-assembly to applications. Chemical Society Reviews, 41(22), 7333–7335. Dan, K., & Yeh, H.L. (2024). Biological activity of polyoxometalates and their applications in anti-aging. Medical Research Archives, 12(12), 1924–2375. De Oliveira, P., Delgado, M. R., & Neves, M. G. P. (2021). In-situ spectroscopic characterization of polyoxometalate catalysts: Mechanistic insights and structure-activity correlations. Journal of Catalysis, 398, 75–92. Dolbecq, A., Dumas, E., Mayer, C. R., & Mialane, P. (2010). Hybrid organic-inorganic polyoxometalate compounds: From structural diversity to applications. Chemical Reviews, 110(7), 6009–6048. Fu, J., Ji, Y., & Wu, J. (2022). Polyoxometalate-based materials for biofilm inhibition and eradication: Mechanistic insights and practical applications. ACS Applied Materials & Interfaces, 14(12), 14522–14534. Gao, J., Toma, F. M., & Ager, J. W. (2017). Polyoxometalate-based molecular catalysts for electrochemical CO2 reduction and sustainable fuel generation. Energy & Environmental Science, 10(4), 1034–1055. Gong, Y., Hu, Q., Wang, C., Zang, L., & Yu, L. (2016). Stimuli-responsive polyoxometalate/ionic liquid supramolecular spheres: Fabrication, characterization, and biological applications. Langmuir, 32(2), 421–427. Gu, J., Zhang, L., Yuan, X., Chen, Y.G., Gao, X., Li, D., & Li, D. (2018). Synthesis and antibacterial activity of polyoxometalates with different structures. Bioinorganic Chemistry and Applications, 9342326. He, D., Jiang, Y., Guillen-Soler, M., Geary, Z., Vizcaino-Anaya, L., Salley, D., Gimenez-Lopez, M. C., Long, D., & Cronin, L. (2024). Algorithm-driven robotic discovery of polyoxometalate-scaffolding metal–organic frameworks. Journal of the American Chemical Society, 146(42), 28952–28960. Hill, C. L. (1998). Introduction: Polyoxometalates multicomponent molecular vehicles to probe fundamental issues and practical problems.Chemical Reviews, 98(1), 1–2. Hu, C., Zhang, J., & Zhao, Y. (2021). Polyoxometalate-metal-organic framework composites for catalysis and energy applications. Chemical Society Reviews, 50(3), 1522–1586. Huang, L., Wu, D., & Yang, K. (2022). Polyoxometalates in energy storage: Advances in batteries and supercapacitors. Energy Storage Materials, 45, 378–395. Iftikhar, T., & Rosnes, M. H. (2024). Covalent organic–inorganic polyoxometalate hybrids in catalysis. Frontiers in Chemistry, 12, 1447623. Ji, Y., Huang, L., Hu, J., Streb, C., & Song, Y. F. (2015). Polyoxometalate-functionalized nanocarbon materials for energy conversion, energy storage and sensor systems. Energy & Environmental Science, 8(3), 776–789. Judeinstein, P. (1992). Synthesis and properties of polyoxometalates based inorganic–organic polymers. Chemistry of Materials, 4(1), 1–7. Keggin, J. F. (1934). Structure of the molecule of 12-phosphotungstic acid. Nature, 134, 785– 786. Kibler, A. J., Tsang, N., Winslow, M., Argent, S. P., Lam, H. W., Robinson, D., & Newton, G. N. (2023). Electronic structure and photoactivity of organoarsenic hybrid polyoxometalates. Inorganic Chemistry, 62(8), 3585–3591. Kortz, U., Todea, A. M., & Vlachogiannakis, G. (2018). Lacunary polyoxometalates: Building blocks for functional materials. Inorganic Chemistry, 57(19), 12291–12305. Kozhevnikov, I. V. (1998). Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chemical Reviews, 98(1), 171–198. Kulesza, P. J., Faulkner, L. R., & Anson, F. C. (1987). Multi-electron redox chemistry of polyoxometalates. Journal of the American Chemical Society, 109(22), 6239–6246. Lan, J., Wang, Y., Huang, B., Xiao, Z., & Wu, P. (2021). Application of polyoxometalates in photocatalytic degradation of organic pollutants. Nanoscale Advances, 3(16), 4646–4658. Li, T., Miras, H. N., &Song, Y.F. (2017). Polyoxometalate -Layered Double Hydroxides Composite Materials: Design and Catalytic Applications.Catalysts,7(9), 260. Lin, Y., & Li, H. (2020). Carbon-based supports for polyoxometalate catalysts: Advances and perspectives. Applied Catalysis B: Environmental, 270, 118857. Long, D. L., Burkholder, E., & Cronin, L. (2007). Polyoxometalate clusters, nanostructures, and materials: From self-assembly to designer materials and devices. Chemical Society Reviews, 36(1), 105–121. Long, D. L., Tsunashima, R., & Cronin, L. (2010). Polyoxometalates: Building blocks for functional nanoscale systems. Angewandte Chemie International Edition, 49(10), 1736– 1758. Lv, H., Geletii, Y. V., Zhao, C., Vickers, J. W., Zhu, G., Luo, Z., & Hill, C. L. (2012). Polyoxometalate water oxidation catalysts and the role of metal substitution in tuning electrocatalytic performance. Chemical Society Reviews, 41(22), 7572–7589. Mahmoud, M. E., Abdelfattah, A. M., & Seleim, M. M. (2022). Nanocomposite materials integrating polyoxometalates for enhanced heavy metal removal. Journal of Environmental Chemical Engineering, 10(2), 107261. Matsumoto, T., & Sadakane, M. (2021). Bio-inspired design of polyoxometalate catalysts: Mimicking natural enzymatic systems. Accounts of Chemical Research, 54(9), 2101– 2113. Miras, H. N., Vila-Nadal, L., & Cronin, L. (2014). Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 43(16), 5679–5699. Miras, H. N., Yan, J., Long, D.-L., & Cronin, L. (2012). Engineering polyoxometalates with emergent properties.Chemical Society Reviews, 41(22), 7403–7430. Misono, M. (2001). Heterogeneous catalysis by heteropoly compounds of molybdenum and tungsten. Catalysis Reviews, 43(3), 325–381. Muller, A., & Peters, F. (2010). Polyoxomet