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Comparison of Atomic Absorption Spectrophotometry (AAS) and X-ray Fluorescence (XRF) for Trace Heavy Metals Analysis in Oguta Lake Water, Imo State, Nigeria

Igbomezie Maryann Chioma, Obiagwu Ifeoma Chinwendu, Ezekoye Miracle, Oluchukwu, Nnadozie Chukwuemeka Fortunatus, Azubuike Gladstone Otuuh, and Kalu, Samuel Anthonio

Abstract

This study compared Atomic Absorption Spectrophotometry (AAS) and X-ray Fluorescence (XRF) for determining trace heavy metals (Pb, Fe, Co, Ag, Ti, Cr, Cu, V, Zn, Mn, Ni) in Oguta Lake, Nigeria, during dry and rainy seasons. A total of 18 water samples (3 sites × 2 seasons × 3 replicates) were analyzed. AAS exhibited superior sensitivity and reproducibility, while XRF offered faster throughput and lower costs. A significant discrepancy was observed for Cu, where XRF reported inflated values due to matrix effects. Concentrations of Pb, Fe, and Zn measured by AAS exceeded WHO permissible limits for drinking water, indicating ecological and health risks. We conclude that AAS is more reliable for regulatory compliance, while XRF is useful for rapid screening. A hybrid approach combining both methods is recommended for effective monitoring.

Keywords

Atomic Absorption Spectrophotometry (AAS)X-ray Fluorescence (XRF)Heavy

References

Ashford, I. (2025). Heavy metal concentrations in Ikere Gorge Dam water, Iseyin, Southwestern Nigeria. Discover Water, 5(14), 1–12. https://doi.org/10.1007/s43832-025-00202-4 Ekeanyanwu, R. C., Nwokedi, C. L., & Noah, U. T. (2015). Monitoring metals in Tilapia tissues, sediments, and water from Nworie River and Oguta Lake. African Journal of Environmental Science and Technology, 9(8), 682–690. https://doi.org/10.5897/AJEST2015.1926 Laperche, V., & Lemière, B. (2021). Possible pitfalls in the analysis of minerals and loose materials by portable XRF, and how to overcome them. Minerals, 11(1), 33. https://doi.org/10.3390/min11010033. Lemière, B. (2018). A review of pXRF (field portable X-ray fluorescence) applications for applied geochemistry. Journal of Geochemical Exploration, 188, 350–363. https://doi.org/10.1016/j.gexplo.2018.02.006. Ohaturuonye, S. O., Okeke, P. A., & Igwe, G. W. (2024). Evaluation of heavy metal levels in water and sediment samples from Oguta Lake, Imo State, Nigeria. International Journal of Water Research, 6(3), 44–53. https://doi.org/10.36266/IJWR/168 Tiihonen, T. E., Nissinen, T. J., Turhanen, P. A., Vepsäläinen, J. J., Riikonen, J., & Lehto, V.-P. (2022). Real-time on-site multielement analysis of environmental waters with a portable X-ray fluorescence (pXRF) system. Analytical Chemistry, 94(34), 11739–11744. https://doi.org/10.1021/acs.analchem.2c01490. U.S. Environmental Protection Agency. (2007). Method 6200: Field portable X-ray fluorescence spectrometry for the determination of elemental concentrations in soil and sediment (EPA/600/R-07/031). https://www.epa.gov/sites/default/files/2015- 12/documents/6200.pdf. Ukiwe, L. N., Nwoko, C. I. A., Egereonu, U. U., & Ukachukwu, S. N. (2015). Assessment of seasonal physico-chemical parameters of Oguta Lake, Nigeria. Journal of Advances in Chemistry, 11(7), 3824–3832. https://doi.org/10.24297/jac.v11i7.2199 Uzukwu, E. M., Davies, I. C., Ogueri, C., & Sulaiman, Y. (2024). Appraisal of heavy metal contamination in fish tissues from Oguta Lake using AAS. Scientia Africana, 23(3), 102– https://doi.org/10.4314/sa.v23i3.440 Weindorf, D. C., Zhu, Y., McDaniel, P., Valerio, M., Lynn, L., Michaelson, G., & Ping, C. L. (2014). Characterizing soils via portable X-ray fluorescence spectrometer: 3. Soil reaction (pH). Geoderma, 232–234, 141–147. https://doi.org/10.1016/j.geoderma.2014.05.005 World Health Organization (WHO). (2017). Guidelines for drinking-water quality (4th ed.). WHO. https://www.who.int/publications/i/item/9789241549950

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