INTERNATIONAL JOURNAL OF CHEMISTRY AND CHEMICAL PROCESSES (IJCCP )

E-I SSN 2545-5265
P- ISSN 2695-1916
VOL. 11 NO. 2 2025
DOI: 10.56201/ijccp.vol.11.no2.2025.pg20.30


Physicochemical Assessment of Oil-Impacted Soils in Idu Ekpeye Community, Ahoada West, Rivers State, Nigeria

Okidhika, Clinton Umebhidhi PhD, Abule, Esther Chinyere PhD


Abstract


This study evaluates the physicochemical properties of oil-polluted farmlands in Idu Ekpeye Community, Ahoada West Local Government Area, Rivers State, Nigeria. Comparative analyses were performed on three polluted sites (Oloya, Uyalena, and Iloh farmlands) and a control site (Uyanye-Enweozu farmland). The results showed significantly reduced pH levels in polluted sites (4.75, 4.19, and 4.32, respectively) compared to the control (5.43). Electrical conductivity peaked at 253 µS/cm in Oloya, indicating increased ionic content. Chloride concentrations were elevated in Oloya (107.77 mg/kg) and Iloh (99.26 mg/kg), compared to the control (53.88 mg/kg). Sulphate values were highest in Oloya (10,500 mg/kg), followed by Iloh (8,400 mg/kg), while the control recorded 7,750 mg/kg. Total hydrocarbon content was significantly high in Uyalena (1,864 mg/kg) and Oloya (381.33 mg/kg), while the control was negligible (-0.0045 mg/kg). Iron (Fe) concentrations ranged from 2,832.81 mg/kg (Oloya) to 10,844.38 mg/kg (Iloh), with the control at 6,433.59 mg/kg. Other metals like Zinc (Zn), Manganese (Mn), Nickel (Ni), Copper (Cu), and Lead (Pb) also showed spatial variability, with Pb being absent in the control but reaching 5.00 mg/kg in Oloya and Uyalena. The results reveal that oil pollution significantly alters soil chemistry, posing ecological and agricultural threats.


keywords:

Oil pollution, Soil quality, Heavy metals, Hydrocarbon contamination, Physicochemical parameters, Idu Ekpeye, Ahoada West, Environmental impact.


References:


Abii, T. A., Ofor, O. F., & Ekpo, C. I. (2023). Effect of organic and microbial amendments on
petroleum hydrocarbon degradation in crude oil-contaminated soils. Environmental
Monitoring and Assessment, 195(2), 134. https://doi.org/10.1007/s10661-023-10789-
Afolabi, A. S., & Oladoja, N. A. (2022). Remediation of petroleum hydrocarbon-contaminated
soil by integrated physicochemical and biological approaches. Journal of Environmental
Management, 315, 115118. https://doi.org/10.1016/j.jenvman.2022.115118
Afolabi, O. S., & Oladoja, N. A. (2022). Health risk assessment of trace metals in agricultural soils
and food crops in oil-producing areas. Environmental Science and Pollution Research,
29(3), 4567–4583. https://doi.org/10.1007/s11356-021-15793-4
Aghamelu, O. P., Egboka, B. C. E., & Onu, N. N. (2022). Geochemical assessment of soils from
petroleum-impacted farmlands in southern Nigeria. Environmental Earth Sciences, 81(5),
https://doi.org/10.1007/s12665-022-10309-4
Akintunde, M. A., Oyekunle, J. A. O., & Popoola, O. E. (2023). Soil heavy metal pollution from
artisanal refining activities in the Niger Delta region: implications for human health.
Environmental
Science
and
Pollution
Research,
30(12),
35817–35829.
https://doi.org/10.1007/s11356-022-23078-0
Akintunde, O. M., Owolabi, A. T., & Adeyemo, A. O. (2023). Zinc bioavailability and
phytotoxicity in contaminated agricultural soils. Environmental Quality Management,
32(1), 75–85. https://doi.org/10.1002/eqm.22456
Anoliefo, G. O., Ikhajiagbe, B., & Okonokhua, B. O. (2022). Effects of soil acidity and heavy
metals on agricultural productivity in oil-polluted farmlands in the Niger Delta. Journal of
Soil
Science
and
Environmental
Management,
13(4),
75–84.
https://doi.org/10.5897/JSSEM2022.0921
AOAC (2019). Official methods of analysis of Association of Official Analytical Collaboration
(AOAC) international (21st edition). Rockwille, MD: AOAC international. Method 973.03-
Chloride (in soil).
APHA (2017). Standard Methods for the Examination of Water and Wastewater, 23rd Edition.
Method 4500-H+B, Electronic Method.
APHA (2017). Standard methods for the examination of water and wastewater (23rd edition).
Washinton, DC, American Public Health Association. Method 5520E- Petroleum
Hydrocarbons (UV Spectrophotometric Method.
ASTM (2018). ASTM international Standard Test Methods for Sulphate ion in Water (ASTM
D516-16). West Conshohocken, PA: ASTM International. https://doi.or/10.1520/D0516-
16
Bassey, J. E., & Ogbonna, O. N. (2021). Heavy metal bioaccumulation in crops: Health
implications for communities in oil-polluted areas of the Niger Delta. Tropical Journal of
Environmental
Science
and
Technology,
25(4),
116–
https://doi.org/10.4314/tjest.v25i4.10
Chikere, C. B., Chikere, B. O., & Okpokwasili, G. C. (2022). Effects of nickel toxicity on soil
microflora and agricultural sustainability. African Journal of Environmental Science and
Technology, 16(2), 58–66. https://doi.org/10.5897/AJEST2021.3050
Chikere, C. B., Okpokwasili, G. C., & Chikere, B. O. (2022). Bioremediation potentials of
autochthonous hydrocarbon-utilizing bacteria in petroleum-polluted soils. International
Journal
of
Environmental
Science
and
Technology,
19(3),
2315–2330.
https://doi.org/10.1007/s13762-021-03370-1
Duru, E. J. C., & Ezirim, E. C. (2023). Environmental justice and crude oil pollution in the Niger
Delta: The urgent need for sustainable policy reforms. African Journal of Environmental
Law and Policy, 25(1), 52–68.
Eze, J. N., & Adieze, I. E. (2022). Toxicological effects of excess zinc exposure on human health
through dietary intake. Journal of Public Health and Environmental Toxicology, 7(1), 41–
https://doi.org/10.9734/jphet/2022/v7i130172
Gbenro, J. A., Adeyemi, A. A., & Ogunleye, B. O. (2021). Ameliorative effect of biochar on
physicochemical properties of petroleum-contaminated soils in Nigeria. Environmental
Technology & Innovation, 24, 102015. https://doi.org/10.1016/j.eti.2021.102015
Jackson, M.L. (2015). Soil chemical analysis: Advanced course (2nd ed.). Madison, WI: University
of Wisconsin, Department of Soil Science.
Korie, M. C., & Akpokodje, E. G. (2022). Soil fertility and contamination assessment in crude oil-
polluted sites of the Niger Delta region. Journal of Environmental Quality, 51(5), 1201–
https://doi.org/10.1002/jeq2.20396
Korie, M. C., & Akpokodje, E. G. (2022). Copper contamination in agricultural fields:
Bioavailability, toxicity, and remediation strategies. Environmental Chemistry Letters,
20(6), 2833–2849. https://doi.org/10.1007/s10311-022-01420-6
Nwachukwu, O. I., & Eze, J. I. (2021). Manganese exposure in agricultural workers and
neurological health outcomes in the Niger Delta. International Journal of Occupational and
Environmental Medicine, 12(4), 215–224. https://doi.org/10.34172/ijoem.2021.2413
Nwachukwu, S. C. U., & Eze, I. L. (2021). Soil microbial diversity and physicochemical
characteristics in response to oil spill and remediation in Ogoniland, Nigeria.
Environmental Sustainability, 4(3), 419–428. https://doi.org/10.1007/s42398-021-00177-
3
Nwofor, E. C., Ebere, N., & Ugwu, M. N. (2023). Elevated iron levels in oil-impacted soils:
Implications for microbial diversity and crop productivity. Soil Systems, 7(1),
https://doi.org/10.3390/soilsystems7010028
Obasi, R. A., & Nduka, I. C. (2022). Heavy metal levels in soil and food crops in oil-producing
communities of Rivers State, Nigeria. Environmental Monitoring and Assessment, 194(6),
https://doi.org/10.1007/s10661-022-10117-6
Obasi, R. A., & Nduka, J. C. (2022). Iron dynamics and its interaction with soil nutrients under oil
contamination stress. African Journal of Agricultural Research, 17(6), 839–
https://doi.org/10.5897/AJAR2022.15880
Olagoke, O. J., Nwachukwu, M. I., & Ogunwale, T. B. (2020). Nickel accumulation in crops and
potential genotoxic risks in South-South Nigeria. Journal of Toxicology and Risk
Assessment, 6(3), 1–9. https://doi.org/10.29011/JTRA-124.100024
Olowokere, M. T., Jimoh, M. A., & Ayeni, L. S. (2020). Influence of organic and inorganic
amendments on growth and heavy metal uptake by maize in crude oil-polluted soils.
Heliyon, 6(7), e04458. https://doi.org/10.1016/j.heliyon.2020.e04458
Omokaro, O. S., & Okieimen, F. E. (2023). Crude oil contamination effects on soil chemical
properties and remediation using cow dung. Journal of Environmental Protection, 14(2),
157–171. https://doi.org/10.4236/jep.2023.142010
Onwumere, B. G., Nnaji, C. C., & Anya, A. O. (2021). Assessment of ecological risks from heavy
metals in oil-impacted soils of Rivers State, Nigeria. Environmental Risk Assessment and
Remediation, 5(3), 124–132. https://doi.org/10.4066/2529-8046.100040
Ugochukwu, C. N. C., & Ertel, J. (2022). Negative impacts of oil pollution on agricultural soil and
crop yield in the Niger Delta, Nigeria. Environmental Management, 70(2), 265–279.
https://doi.org/10.1007/s00267-021-01541-4
USEPA (2007). United States Environmental Protection Agency Method 3051A: Microwave
assisted acid digestion of sediments, sludges, soils and oils (Revision 1). Washinton , DC:
U.S Environmental Protection Agency.


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