International Journal of Engineering and Modern Technology (IJEMT )

E-ISSN 2504-8848
P-ISSN 2695-2149
VOL. 10 NO. 10 2024
DOI: 10.56201/ijemt.v10.no10.2024.pg44.52


Effect of Carbon Fillers on Water Absorption in Polypropylene- Chitosan Composites for Fuel Cells

Adebayo, Stephen Oluwamuyiwa, Adelaja, Oluwaseun A., Babatola, J. O.


Abstract


This study examines the water absorption characteristics of polypropylene-chitosan composites modified with conductive fillers to assess their potential for fuel cell applications, where both conductivity and moisture resistance are critical. Nine composite samples were prepared: a control sample (AX) containing only polypropylene and chitosan nanoparticles, and eight experimental samples divided into two groups with varying concentrations (5-20%) of either activated carbon (B1-B4) or graphene (C1-C4) as conductive fillers. Water absorption was measured over seven days to evaluate how each filler type and concentration impacted moisture uptake. Results showed that the control sample exhibited the lowest water absorption, underscoring the inherent moisture resistance of the polypropylene-chitosan matrix. However, the absence of conductive fillers in AX limits its potential for fuel cell applications. Among the activated carbon-enhanced samples, Sample B2 (10% activated carbon) demonstrated the most favorable balance of moderate water absorption and potential conductivity. In the graphene group, Sample C2 (10% graphene) displayed a similar balance, with stable moisture resistance and likely enhanced electrical conductivity due to graphene’s properties. Higher filler concentrations in both groups increased water absorption, suggesting that excessive filler can introduce porosity, thereby reducing material stability. The findings indicate that composites containing 10% conductive filler—either activated carbon or graphene—are optimal, combining moisture resistance with expected conductivity. These materials show promise for further testing in fuel cell environments, where their properties could support both durability and performance.


keywords:

Plastic wastes (PP), Activated carbon, Graphene, Water Absorption, Waste-to-energy,


References:


Adelaja, O. (2015). Bioremediation of petroleum hydrocarbons using microbial fuel cells.

A PhD thesis submitted at the University of Westminster. Accessed from

(http://westminsterresearch.wmin.ac.uk/).
Adelaja, O.A., Udorah, D. O., Babaniyi, B.R., Babatola, J.O. (2024). Development of PET?AC

Composite: Effect of Preparation Method on the Mechanical and Water Absorption,

Behaviours. Springer: Chemistry Africa, 1-16. https://doi.org/10.1007/s42250-023-

00852-8).
Balandin, A. A., Hosseini, S., Rezai, A., and Moradi, R et al. (2011). Thermal properties of

graphene
and nanostructured carbon
materials. Nature Materials, 10(8), 569-581.
Bolotin, K. I., Lee, S., Ma, C. C. (2008). Ultrahigh electron mobility in suspended graphene. Solid

State Communications, 146(9-10), 351-355.
Chen, L., Yang, C., and Huang, T. (2019). Conductive Properties of Polymer Composites for Fuel

Cell Applications. Composite Science Journal, 39(3), 205-215.

Geethapriya, D., and Barathan, S. (2016). Synthesis of activated carbon, magnesium oxide,

magnesium oxide impregnated activated carbon nanoparticles and their antibacterial

activity. Der Pharma Chemica, 8(19):572-580
Gopi, S., Balakrishnan, P., Rajamani, R., and Kulkarni, P. (2017). Effect of chitosan nanoparticle

reinforcement on the water absorption behavior of polymer composites. Composites

Science and Technology, 15:8-16.
Gupta, A., Buchmeiser, M. R., Rosler, J., and Eppinger, A (2018). Polypropylene-based

composites
for high-performance applications. Journal of Applied Polymer Science,

135(5), 1234- 1242.
Isil, G., Yavuz, G., and Zeki, A. (2016). Waste tea derived activated carbon/polyaniline

Composites as Supercapacitor Electrode. 5th International Conference on Renewable

Energy Research and Application, 20-23 Nov 2016, Birmingham UK.
Nguyen, C. T., Ma, M., Hu, W., and Chen, S (2021). Chitosan composites in renewable energy

devices. International Journal of Energy Research, 45(4), 5601-5615.
Park, S. H., Rzeczkowski, A., La Mantia, F. (2019). Durability of conductive polymer composites

for electrochemical
devices. Energy and Environmental Science, 12(7), 2159-2173.
Schweitzer, B., Florez, J., and Simao, R. (2019). Carbon-based conductive fillers for fuel cells:

Water absorption and performance metrics. Energy Science and Engineering, 7(1), 123-
Stepashkina, A. S., Tsobkallo, E. S. and Alyoshin, A. N. (2014). Electrical Conductivity Modeling

and Research of Polypropylene Composites Filled with Carbon Black. Journal of Physics:

Conference Series. 16th Russian Youth Conference on Physics and Astronomy.
Surya, K. and Micheal, M.S. (2021). Hierarchical porous AC prepared from biowaste of lemon

peel for electrochemical double layer capacitor. Journal of biomass and bioenergy,

152:106175
Udorah, D. O., Adelaja, O. A., Babatola, J. O. (2023). Investigating the Water Absorption

Behavior of Biocomposites containing Activated Carbon And Plastic Waste For Fuel Cell

Application. International Journal of Research and Publication, 2(5):238-247.
Weng, C. C., Tsai, H. M., and Ma, C. M. (2012). Enhanced Conductivity in

Graphene/Polypropylene Composites. Advanced Functional Materials, 18(3), 456-467.
Yong, C., Zhao, L et al. (2022). Moisture resistance in chitosan-based biocomposites. Journal of

Polymer Science, 60(5), 345-353.
Zhao, Z., Tang, Y., and Wang, H. (2020). Automotive Applications of Polymer-Based Fuel Cell

Materials. Journal of Automotive Technology, 47(6), 671-679.


DOWNLOAD PDF

Back


Google Scholar logo
Crossref logo
ResearchGate logo
Open Access logo
Google logo