INTERNATIONAL JOURNAL OF CHEMISTRY AND CHEMICAL PROCESSES (IJCCP )

E-I SSN 2545-5265
P- ISSN 2695-1916
VOL. 10 NO. 4 2024
DOI: 10.56201/ijccp.v10.no4.2024.pg21.31


Ecological Risk Factor (E ), Potential Ecological Risk Index (RI) and Enrichment factor Ecological Risk Factor (E F ), Potential Ecological Risk Index (RI) and Enrichment factor assessment of Selected Heavy Metals in Sediments of Kaani River, Ogoni axis, Rivers State, Nigeria.

Anate, S. Ganiyu ; Momta, P. NukebaBari ; Ndifreke, B. Nde ; Amacha, Mathew


Abstract


The community's residents have traditionally exploited the fresh water of the Kaani River for home and agricultural uses. Surface sediment samples were taken from four stations: Maa di Binnise Igbara water side (station 1), Mann stream (station 2), Woman stream (station 3), and Nwii ke ma kor stream (station 4). The samples were then digested and subjected to an atomic absorption spectrophotometric method to determine the concentrations of certain heavy metals. The order of metal concentrations were iron (Fe) > zinc (Zn) > lead (Pb) > chromium (Cr) > nickel (Ni) > copper (Cu) > manganese (Mn) > arsenic (As) > cadmium (Cd), according to the obtained data. Fe was [124.981±2.673]mg/kg, Zn was [36.356±1.593]mg/kg, Pb was [7.647±0.081]mg/kg, Cr was [6.361±0.074]mg/kg, Ni was [5.734±0.024]mg/kg, Cu was [5.541±0.071]mg/kg, Mn was [4.000±0.021]mg/kg, As was [0.182±0.002]mg/kg, and Cd was [0.049±0.002] mg/Kg, according to their respective mean values. A few model indices (contamination factor, ecological risk factor, possible ecological risk index, and enrichment factor) were used to further assess the results. The sediments were found to be somewhat contaminated, according to an examination of sediment contamination factors. According to an ecological risk assessment, the metals are safe for the ecosystem at the current quantities. All of the metals, with the exception of Cd in Nwii ke Ma Kor Stream (station 4) and Fe at Mann Stream (station 2), had considerable anthropogenic enrichment at the various stations, according to enrichment factor analysis. Thus, it is important to implement sufficient and ongoing monitoring to stop the introduction of an increased amount of anthropogenic heavy metals into the river.


keywords:

contaminant, Possible Ecological Risk Index, Ecological Risk Factor, and


References:


Aghoghovwia, O. A., Oyelese, O. A., & Ige Ohimain, E. I. (2015). Heavy metal levels in water
and sediment of Warri River, Niger Delta, Nigeria. International Journal of Geology,
Agriculture and Environmental Sciences, 3(1), 20-24.
Ahmad, W., Alharthy, R. D., Zubair, M., Ahmed, M., Hameed, A., & Rafique, S. (2021). Toxic
and heavy metals contamination assessment in soil and water to evaluate human health
risk. Scientific Representations, 17006.
Aloupi, M., & Angelidis, M. O. (2001). Geochemistry of natural and anthropogenic metals in the
coastal sediments of the Island of Lesvos, Aegean Sea. Environmental Pollution, 113, 211–
219.
Ama, I. N., Nwajei, G. E., & Agbaire, P. O. (2017). Distribution of trace elements in surface water
and sediments from Warri River in Warri, Delta State of Nigeria. World News of Natural,
11, 65-82.
Benson, N. U., Asuquo, F. E., Williams, A. B., Essien, J. P., Ekong, C. I., Akpabio, O., & Olajire,
A. A. (2016): Source evaluation and trace metal contamination in benthic sediments from
equatorial ecosystems using multivariate statistical techniques. Plos One, 11(6), 1–19.
Bibi, M. H., Ahmed, F., & Ishiga, H. (2007). Assessment of metal concentrations in lake sediments
of southwest Japan based on sediment quality guidelines. Environmental Geology, 52(7),
625–639.
Buat-Menard, P., & Chesselet, R. (1979). Variable influence of the atmospheric flux on the trace
metal chemistry of oceanic suspended matter. Earth Planet and Science Letters, 42(3),
399–411.
Davies, O. A., & Abolude, D. S. (2016). Polycyclic Aromatic Hydrocarbons (Pahs) of Surface
Water from Oburun Lake, Niger Delta, Nigeria. Applied Science Reports, 13(1), 20-24.
Edori, OS; Kpee, F (2016). Physicochemical and heavy metal assessment of water samples from
boreholes near some abattoirs in Port Harcourt, Rivers State, Nigeria. American Chemical
Science Journal, 14(3): 1- 8.
Edori, OS; Kpee, F (2017). Assessment Models for Heavy Metal Pollution in Soils within Selected

Abattoirs in Port Harcourt, Rivers State, Nigeria. Singapore Journal of Applied Research,
7(1): 9-15.
Edori, OS; Kpee, F (2018). Assessment of heavy metals content in water at effluents discharge
points into the New Calabar River, Port Harcourt, Southern Nigeria. Global Journal of
Scientific Frontier Research, (B), 18(2): 52-58.
Edori, O. S., Edori, E. S., & Ntembaba, S. A. (2020). Assessment of heavy metals concentrations
in sediments at drainage discharge points into the New Calabar River, Rivers State, Nigeria.
International Journal of Research and Innovation in Applied Science, 5(10), 9-13.
Edward, M., & Muhib, A. (2020). Heavy Metals Concentration in Water, Sediment, and Fish
around Escravos River, Nigeria. World Journal of Research and Review (WJRR), 10(2),
28-37.
Håkanson, L. (1980). Ecological risk index for aquatic pollution control, a sedimentological
approach. Water Research, 14(5), 975 - 1001.
Han, YM; Du, PX; Cao, JJ; Posmentier, ES (2006). Multivariate analysis of heavy metal
contamination in urban dusts of Xi’an, Central China. Scientific Tot. Environment, 355,
176–186.
Lacatusu, R. (2000). Appraising levels of soil contamination and pollution with heavy metals.
European Soil Bureau Research Report, 4(1), 393-402.
Mohamaden, MII; Khalil, MK; Draz, SEO; Hamoda, AZM (2017). Ecological risk assessment and
spatial distribution of some heavy metals in surface sediments of New Valley, Western
Desert, Egypt. Egyptian Journal of Aquatic Research, 43: 31-43.
Nwajei, G. E., Dibofori-Orji, A. N., Iwegbue, C. M. A., & Ojuh, B. O. (2014). Distribution of trace
elements in surface water and sediments from Crayford Creek in Warri, Delta State of
Nigeria. Academic Research International, 5(2), 123–134.
Ogoyi, D. O., Mwita, C. J., Nguu, E. K., & Shiundu, P. M. (2011). Determination of Heavy Metal
Content in Water, Sediment and Microalgae from Lake Victoria, East Africa. The Open
Environmental Engineering Journal, 4(1), 156-161.
Olayinka, O. O., Akande, O. O., Bamgbose, K., & Adetunji, M. T. (2017). Physicochemical
characteristics and heavy metal levels in soil samples obtained from selected anthropogenic
sites in Abeokuta, Nigeria. Journal of Applied Science and Environmental Management,
21(5), 883-891.
Orisakwe, O. E., Igweze, Z. N., Okolo, K. O., & Udowelle, N. A. (2015). Human health hazards of
poly aromatic hydrocarbons in Nigerian smokeless tobacco. Toxicology Reports 2, 8(3),
1019-1023.
Pinedo, S., Jordana, E., Monia Flagella, M., & Ballesteros, E. (2014). Relationships between heavy
metals contamination in shallow marine sediments with industrial and urban development in
Catalonia (Northwestern Mediterranean Sea). Water Air and Soil Pollution, 225(9), 208-
225.
Robin, R. S., Muduli, P. R., Vardhan, K. V., Ganguly, D., & Abhilash, K. R. (2012). Heavy metal
contamination and risk assessment in the marine environment of Arabian Sea, along the
Southwest Coast of India. American Journal of Analytical Chemistry, 2(1), 191–208.
Saeed, S., Marzieh, V. D., Akbar, H., & Toba, K. (2004). Heavy Metals in Water and Sediment: A
Case Study of Tembi River Journal of Environmental and Public Health, 20(14), 76-86.
Saha, PK; Hossain, MD (2011). Assessment of Heavy Metal Contamination and Sediment Quality
in the Buriganga River, Bangladesh. Intern. Conf. Environ. Sci. Techn. Singapore, 6: 384-
388.
Shomar, B. H., Muller, G., & Yahya, A. (2005). Seasonal variations of chemical composition of
water and bottom sediments in the wetland of Wadi Gaza, Gaza Strip. Wetlands Ecology
and Manageme13nt, 13(2), 419-431.
Tao, Y., Yao, S., Xue, B., Deng, J., Wang, X., Feng, M., & Hu, W. (2010). Polycyclic aromatic
Hydrocarbons in surface sediments from drinking water sources of Taihu Lake, China:
Sources, partitioning and toxicological risk. Journal of Environmental Monitoring, 12(3),
2282–2289.
Varol, M. (2011). Assessment of heavy metal contamination in sediments of the Tigris River
(Turkey) using pollution indices and multivariate statistical techniques. Journal of Hazard
Material, 195(3), 355–364.


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